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Acid rain is a rain or any other form of precipitation that is unusually acidic, meaning that it possesses elevated levels of hydrogen ions (low pH). It can have harmful effects on plants, aquatic animals, and infrastructure. Acid rain is caused by emissions of sulfur dioxide and nitrogen oxides, which react with the water molecules in the atmosphere to produce acids. Governments have made efforts since the 1970s to reduce the release of sulfur dioxide into the atmosphere with positive results. Nitrogen oxides can also be produced naturally by lightning strikes and sulfur dioxide is produced by volcanic eruptions. The chemicals in acid rain can cause paint to peel, corrosion of steel structures such as bridges, and erosion of stone statues.

DefinitionEdit

"Acid rain" is a popular term referring to the deposition of wet (rain, snow, sleet, fog, cloudwater, and dew) and dry (acidifying particles and gases) acidic components. Distilled water, once carbon dioxide is removed, has a neutral pH of 7. Liquids with a pH less than 7 are acidic, and those with a pH greater than 7 are alkaline. “Clean” or unpolluted rain has an acidic pH, but usually no lower than 5.7, because carbon dioxide and water in the air react together to form carbonic acid, a weak acid. However, unpolluted rain can also contain other chemicals which affect its pH. A common example is nitric acid produced by electric discharge in the atmosphere such as lightning.[1] Carbonic acid is formed by the reaction

H2O (l) + CO2 (g) is in equilibrium with H2CO3 (aq)

Carbonic acid then can ionize in water forming low concentrations of hydronium and carbonate ions:

H2O (l) + H2CO3 (aq) is in equilibrium with HCO3 (aq) + H3O+ (aq)

Acid deposition as an environmental issue would include additional acids to H2CO3.

HistoryEdit

File:Waldschaeden Erzgebirge 3.jpg

The corrosive effect of polluted, acidic city air on limestone and marble was noted in the 17th century by John Evelyn, who remarked upon the poor condition of the Arundel marbles.[2] Since the Industrial Revolution, emissions of sulfur dioxide and nitrogen oxides into the atmosphere have increased.[3][4] In 1852, Robert Angus Smith was the first to show the relationship between acid rain and atmospheric pollution in Manchester, England.[5]

Though acidic rain was discovered in 1853, it was not until the late 1960s that scientists began widely observing and studying the phenomenon.[6] The term "acid rain" was coined in 1872 by Robert Angus Smith.[7] Canadian Harold Harvey was among the first to research a "dead" lake. Public awareness of acid rain in the U.S increased in the 1970s after The New York Times published reports from the Hubbard Brook Experimental Forest in New Hampshire of the myriad deleterious environmental effects shown to result from it.[8][9]

Occasional pH readings in rain and fog water of well below 2.4 have been reported in industrialized areas.[3] Industrial acid rain is a substantial problem in China and Russia[10][11] and areas downwind from them. These areas all burn sulfur-containing coal to generate heat and electricity.[12]

The problem of acid rain has not only increased with population and industrial growth, but has become more widespread. The use of tall smokestacks to reduce local pollution has contributed to the spread of acid rain by releasing gases into regional atmospheric circulation.[13][14] Often deposition occurs a considerable distance downwind of the emissions, with mountainous regions tending to receive the greatest deposition (simply because of their higher rainfall). An example of this effect is the low pH of rain which falls in Scandinavia.[15]

History of acid rain in the United StatesEdit

File:Bixi stele (wrapped), Harvard University, Cambridge, MA - IMG 4607.JPG

In 1980, the U.S. Congress passed an Acid Deposition Act.[17] This Act established a 18-year assessment and research program under the direction of the National Acidic Precipitation Assessment Program (NAPAP). NAPAP looked at the entire problem from a scientific perspective. It enlarged a network of monitoring sites to determine how acidic the precipitation actually was, and to determine long term trends, and established a network for dry deposition. It looked at the effects of acid rain and funded research on the effects of acid precipitation on freshwater and terrestrial ecosystems, historical buildings, monuments, and building materials. It also funded extensive studies on atmospheric processes and potential control programs.

From the start, policy advocates from all sides attempted to influence NAPAP activities to support their particular policy advocacy efforts, or to disparage those of their opponents.[17] For the U.S. Government's scientific enterprise, a significant impact of NAPAP were lessons learned in the assessment process and in environmental research management to a relatively large group of scientists, program managers and the public.[18]

In 1991, DENR provided its first assessment of acid rain in the United States. It reported that 5% of New England Lakes were acidic, with sulfates being the most common problem. They noted that 2% of the lakes could no longer support Brook Trout, and 6% of the lakes were unsuitable for the survival of many species of minnow. Subsequent Reports to Congress have documented chemical changes in soil and freshwater ecosystems, nitrogen saturation, decreases in amounts of nutrients in soil, episodic acidification, regional haze, and damage to historical monuments.

Meanwhile, in 1989, the US Congress passed a series of amendments to the Clean Air Act. Title IV of these amendments established the Acid Rain Program, a cap and trade system designed to control emissions of sulfur dioxide and nitrogen oxides. Title IV called for a total reduction of about 10 million tons of SO2 emissions from power plants. It was implemented in two phases. Phase I began in 1995, and limited sulfur dioxide emissions from 110 of the largest power plants to a combined total of 8.7 million tons of sulfur dioxide. One power plant in New England (Merrimack) was in Phase I. Four other plants (Newington, Mount Tom, Brayton Point, and Salem Harbor) were added under other provisions of the program. Phase II began in 2000, and affects most of the power plants in the country.

During the 1990s, research continued. On March 10, 2005, EPA issued the Clean Air Interstate Rule (CAIR). This rule provides states with a solution to the problem of power plant pollution that drifts from one state to another. CAIR will permanently cap emissions of SO2 and NOx in the eastern United States. When fully implemented, CAIR will reduce SO2 emissions in 28 eastern states and the District of Columbia by over 70 percent and NOx emissions by over 60 percent from 2003 levels.[19]

Overall, the Program's cap and trade program has been successful in achieving its goals. Since the 1990s, SO2 emissions have dropped 40%, and according to the Pacific Research Institute, acid rain levels have dropped 65% since 1976.[20][21] However, this was significantly less successful than conventional regulation in the European Union, which saw a decrease of over 70% in SO2 emissions during the same time period.[22]

In 2007, total SO2 emissions were 8.9 million tons, achieving the program's long term goal ahead of the 2010 statutory deadline.[23]

The EPA estimates that by 2010, the overall costs of complying with the program for businesses and consumers will be $1 billion to $2 billion a year, only one fourth of what was originally predicted.[20]

Emissions of chemicals leading to acidificationEdit

The most important gas which leads to acidification is sulfur dioxide. Emissions of nitrogen oxides which are oxidized to form nitric acid are of increasing importance due to stricter controls on emissions of sulfur containing compounds. 70 Tg(S) per year in the form of SO2 comes from fossil fuel combustion and industry, 2.8 Tg(S) from wildfires and 7-8 Tg(S) per year from volcanoes.[24]

Natural phenomenaEdit

The principal natural phenomena that contribute acid-producing gases to the atmosphere are emissions from volcanoes. Thus, for example, fumaroles from the Laguna Caliente crater of Poás Volcano create extremely high amounts of acid rain and fog, with acidity as high as a pH of 2, clearing an area of any vegetation and frequently causing irritation to the eyes and lungs of inhabitants in nearby settlements.[25] Acid-producing gasses are also created by biological processes that occur on the land, in wetlands, and in the oceans. The major biological source of sulfur containing compounds is dimethyl sulfide.

Nitric acid in rainwater is an important source of fixed nitrogen for plant life, and is also produced by electrical activity in the atmosphere such as lightning.

Acidic deposits have been detected in glacial ice thousands of years old in remote parts of the globe.[13]

Soils of coniferous forests are naturally very acidic due to the shedding of needles, and the results of this phenomenon should not be confused with acid rain.

Human activityEdit

File:Gavin Plant.JPG

The principal cause of acid rain is sulfur and nitrogen compounds from human sources, such as electricity generation, factories, and motor vehicles. Electrical power complexes utilising coal are among the greatest contributors to gaseous pollutions that are responsible for acidic rain. The gases can be carried hundreds of kilometers in the atmosphere before they are converted to acids and deposited. In the past, factories had short funnels to let out smoke but this caused many problems locally; thus, factories now have taller smoke funnels. However, dispersal from these taller stacks causes pollutants to be carried farther, causing widespread ecological damage.

Chemical processesEdit

Combustion of fuels produces sulfur dioxide and nitric oxides. They are converted into sulfuric acid and nitric acid.[26]

Gas phase chemistryEdit

In the gas phase sulfur dioxide is oxidized by reaction with the hydroxyl radical via an intermolecular reaction:[5]

SO2 + OH· → HOSO2·

which is followed by:

HOSO2· + O2HO2· + SO3

In the presence of water, sulfur trioxide (SO3) is converted rapidly to sulfuric acid:

SO3 (g) + H2O (l) → H2SO4 (l)

Nitrogen dioxide reacts with OH to form nitric acid:

NO2 + OH· → HNO3

Chemistry in cloud dropletsEdit

When clouds are present, the loss rate of SO2 is faster than can be explained by gas phase chemistry alone. This is due to reactions in the liquid water droplets.

Hydrolysis

Sulfur dioxide dissolves in water and then, like carbon dioxide, hydrolyses in a series of equilibrium reactions:

SO2 (g) + H2O is in equilibrium with SO2·H2O
SO2·H2O is in equilibrium with H+ + HSO3
HSO3 is in equilibrium with H+ + SO32−
Oxidation

There are a large number of aqueous reactions that oxidize sulfur from S(IV) to S(VI), leading to the formation of sulfuric acid. The most important oxidation reactions are with ozone, hydrogen peroxide and oxygen (reactions with oxygen are catalyzed by iron and manganese in the cloud droplets).[5]

Acid depositionEdit

Wet depositionEdit

Wet deposition of acids occurs when any form of precipitation (rain, snow, and so on.) removes acids from the atmosphere and delivers it to the Earth's surface. This can result from the deposition of acids produced in the raindrops (see aqueous phase chemistry above) or by the precipitation removing the acids either in clouds or below clouds. Wet removal of both gases and aerosols are both of importance for wet deposition.

Dry depositionEdit

Acid deposition also occurs via dry deposition in the absence of precipitation. This can be responsible for as much as 20 to 60% of total acid deposition.[27] This occurs when particles and gases stick to the ground, plants or other surfaces.

Adverse effectsEdit

File:Waterspecies.gif

Acid rain has been shown to have adverse impacts on forests, freshwaters and soils, killing insect and aquatic life-forms as well as causing damage to buildings and having impacts on human health.

Surface waters and aquatic animalsEdit

Both the lower pH and higher aluminium concentrations in surface water that occur as a result of acid rain can cause damage to fish and other aquatic animals. At pHs lower than 5 most fish eggs will not hatch and lower pHs can kill adult fish. As lakes and rivers become more acidic biodiversity is reduced. Acid rain has eliminated insect life and some fish species, including the brook trout in some lakes, streams, and creeks in geographically sensitive areas, such as the Adirondack Mountains of the United States.[28] However, the extent to which acid rain contributes directly or indirectly via runoff from the catchment to lake and river acidity (i.e., depending on characteristics of the surrounding watershed) is variable. The United States Environmental Protection Agency's (EPA) website states: "Of the lakes and streams surveyed, acid rain caused acidity in 75 percent of the acidic lakes and about 50 percent of the acidic streams".[28]

SoilsEdit

Soil biology and chemistry can be seriously damaged by acid rain. Some microbes are unable to tolerate changes to low pHs and are killed.[29] The enzymes of these microbes are denatured (changed in shape so they no longer function) by the acid. The hydronium ions of acid rain also mobilize toxins such as aluminium, and leach away essential nutrients and minerals such as magnesium.[30]

2 H+ (aq) + Mg2+ (clay) is in equilibrium with 2 H+ (clay) + Mg2+ (aq)

Soil chemistry can be dramatically changed when base cations, such as calcium and magnesium, are leached by acid rain thereby affecting sensitive species, such as sugar maple (Acer saccharum).[31][32]

Forests and other vegetationEdit

File:Acid rain woods1.JPG

Adverse effects may be indirectly related to acid rain, like the acid's effects on soil (see above) or high concentration of gaseous precursors to acid rain. High altitude forests are especially vulnerable as they are often surrounded by clouds and fog which are more acidic than rain.

Other plants can also be damaged by acid rain, but the effect on food crops is minimized by the application of lime and fertilizers to replace lost nutrients. In cultivated areas, limestone may also be added to increase the ability of the soil to keep the pH stable, but this tactic is largely unusable in the case of wilderness lands. When calcium is leached from the needles of red spruce, these trees become less cold tolerant and exhibit winter injury and even death.[33][34]

Human health effectsEdit

Acid rain does not directly affect human health. The acid in the rainwater is too dilute to have direct adverse effects. However, the particulates responsible for acid rain (sulfur dioxide and nitrogen oxides) do have an adverse effect. Increased amounts of fine particulate matter in the air do contribute to heart and lung problems including asthma and bronchitis.[35]

Other adverse effectsEdit

File:Pollution - Damaged by acid rain.jpg

Acid rain can also damage buildings and historic monuments and statues, especially those made of rocks, such as limestone and marble, that contain large amounts of calcium carbonate. Acids in the rain react with the calcium compounds in the stones to create gypsum, which then flakes off.

CaCO3 (s) + H2SO4 (aq) is in equilibrium with CaSO4 (aq) + CO2 (g) + H2O (l)

The effects of this are commonly seen on old gravestones, where acid rain can cause the inscriptions to become completely illegible. Acid rain also increases the corrosion rate of metals, in particular iron, steel, copper and bronze.[36][37]

Affected areasEdit

Places significantly impacted by acid rain around the globe include most of eastern Europe from Poland northward into Scandinavia,[38] the eastern third of the United States,[39] and southeastern Canada. Other affected areas include the southeastern coast of China and Taiwan.[citation needed]

Prevention methodsEdit

Technical solutionsEdit

Many coal-burning power stations use flue-gas desulfurization (FGD) to remove sulfur-containing gases from their stack gases. For a typical coal-fired power station, FGD will remove 95 percent or more of the SO2 in the flue gases. An example of FGD is the wet scrubber which is commonly used. A wet scrubber is basically a reaction tower equipped with a fan that extracts hot smoke stack gases from a power plant into the tower. Lime or limestone in slurry form is also injected into the tower to mix with the stack gases and combine with the sulfur dioxide present. The calcium carbonate of the limestone produces pH-neutral calcium sulfate that is physically removed from the scrubber. That is, the scrubber turns sulfur pollution into industrial sulfates.

In some areas the sulfates are sold to chemical companies as gypsum when the purity of calcium sulfate is high. In others, they are placed in landfill. However, the effects of acid rain can last for generations, as the effects of pH level change can stimulate the continued leaching of undesirable chemicals into otherwise pristine water sources, killing off vulnerable insect and fish species and blocking efforts to restore native life.

Vehicle emissions control reduces emissions of nitrogen oxides from motor vehicles.

International treatiesEdit

A number of international treaties on the long range transport of atmospheric pollutants have been agreed for example, Sulphur Emissions Reduction Protocol under the Convention on Long-Range Transboundary Air Pollution. Canada and the US signed the Air Quality Agreement in 1991. Most European countries and Canada have signed the treaties.

Emissions tradingEdit

In this regulatory scheme, every current polluting facility is given or may purchase on an open market an emissions allowance for each unit of a designated pollutant it emits. Operators can then install pollution control equipment, and sell portions of their emissions allowances they no longer need for their own operations, thereby recovering some of the capital cost of their investment in such equipment. The intention is to give operators economic incentives to install pollution controls.

The first emissions trading market was established in the United States by enactment of the Clean Air Act Amendments of 1990. The overall goal of the Acid Rain Program established by the Act[40] is to achieve significant environmental and public health benefits through reductions in emissions of sulfur dioxide (SO2) and nitrogen oxides (NOx), the primary causes of acid rain. To achieve this goal at the lowest cost to society, the program employs both regulatory and market based approaches for controlling air pollution.

See alsoEdit

ReferencesEdit

  1. Likens, G. E., W. C. Keene, J. M. Miller and J. N. Galloway. 1987. Chemistry of precipitation from a remote, terrestrial site in Australia. J. Geophys. Res. 92(D11):13,299-13,314.
  2. E. S. de Beer, ed. The Diary of John Evelyn, III, 1955 (19 September 1667) p. 495.
  3. 3.0 3.1 New Science Directorate Bio Mass Burning Redirect
  4. Weathers, K. C. and G. E. Likens. 2006. Acid rain. pp. 1549–1561. In: W. N. Rom (ed.). Environmental and Occupational Medicine. Lippincott-Raven Publ., Philadelphia. Fourth Edition.
  5. 5.0 5.1 5.2 Seinfeld, John H.; Pandis, Spyros N (1998). Atmospheric Chemistry and Physics — From Air Pollution to Climate Change. John Wiley and Sons, Inc. ISBN 978-0-471-17816-3
  6. Likens, G. E., F. H. Bormann and N. M. Johnson. 1972. Acid rain. Environment 14(2):33-40.
  7. EPA: Acid Rain in New England, A Brief History
  8. Likens, G. E. and F. H. Bormann. 1974. Acid rain: a serious regional environmental problem. Science 184(4142):1176–1179.
  9. Search the HBES Publications. Hubbardbrook.org. Archived from the original on 23 November 2010. Retrieved on 2010-11-18.
  10. Galloway, J. N., Zhao Dianwu, Xiong Jiling and G. E. Likens. 1987. Acid rain: a comparison of China, United States and a remote area. Science 236:1559–1562.
  11. chandru (2006-09-09). CHINA: Industrialization pollutes its country side with Acid Rain. Southasiaanalysis.org. Retrieved on 2010-11-18.
  12. [1][dead link]
  13. 13.0 13.1 Likens, G. E., R. F. Wright, J. N. Galloway and T. J. Butler. 1979. Acid rain. Sci. Amer. 241(4):43-51.
  14. Likens, G. E. 1984. Acid rain: the smokestack is the “smoking gun.” Garden 8(4):12-18.
  15. http://www.emep.int/publ/common_publications.html
  16. "Art Under Wraps" , Harvard Magazine, March–April 2000
  17. 17.0 17.1 Lackey (1997) - Science, policy, and acid rain: lessons learned. Renewable Resources Journal. 15(1): 9-13.
  18. [2] - Winstanley (1998). Acid rain: science and policy making. Environmental Science and Policy. 1(1): 51-57.
  19. US EPA: A Brief History of Acid Rain. Epa.gov. Retrieved on 2010-11-18.
  20. 20.0 20.1 'Cap-and-trade' model eyed for cutting greenhouse gases, San Francisco Chronicle, December 3, 2007.
  21. Facts On File News Services Databases. 2facts.com. Retrieved on 2010-11-18.
  22. Gilberston, T. and Reyes, O. 2009. Carbon Trading: how it works and why it fails. Dag Hammerskjold Foundation: 22
  23. Acid Rain Program 2007 Progress Report, United States Environmental Protection Agency, January 2009.
  24. Berresheim, H.; Wine, P.H. and Davies D.D., (1995). Sulfur in the Atmosphere. In Composition, Chemistry and Climate of the Atmophere, ed. H.B. Singh. Van Nostran Rheingold ISBN
  25. Poás Volcano and Laguna Caliente. Wondermondo. 24 October 2010. http://www.wondermondo.com/Countries/NA/CostaRica/Alajuela/PoasCaliente.htm. 
  26. Clean Air Act Reduces Acid Rain In Eastern United States, ScienceDaily, Sept. 28, 1998
  27. UK National Air Quality Archive: Air Pollution Glossary. Airquality.co.uk (2002-04-01). Retrieved on 2010-11-18.
  28. 28.0 28.1 US EPA: Effects of Acid Rain - Surface Waters and Aquatic Animals
  29. Rodhe, H., et al. The global distribution of acidifying wet deposition. Environmental Science and TEchnology. vlo. 36, no. 20 (October) p. 4382-8
  30. US EPA: Effects of Acid Rain - Forests
  31. Likens, G. E., C. T. Driscoll, D. C. Buso, M. J. Mitchell, G. M. Lovett, S. W. Bailey, T. G. Siccama, W. A. Reiners and C. Alewell. 2002. The biogeochemistry of sulfur at Hubbard Brook. Biogeochemistry 60(3):235-316.
  32. Likens, G. E., C. T. Driscoll and D. C. Buso. 1996. Long-term effects of acid rain: response and recovery of a forest ecosystem. Science 272:244-246.
  33. DeHayes, D.H., Schaberg, P.G., and G.R. Strimbeck. 2001. Red Spruce Hardiness and Freezing Injury Susceptibility. In: F. Bigras, ed. Conifer Cold Hardiness. Kluwer Academic Publishers, the Netherlands.
  34. Lazarus, B. E., P. G. Schaberg, G. Hawley and D. H. DeHayes. 2006. Landscape-scale spatial patterns of winter injury to red spruce foliage in a year of heavy region-wide injury. Can. J. For. Res. 36:142-152.
  35. EPA, Effects of Acid Rain - Human Health, 5/13/2009
  36. ICP on effects on materials. Springerlink.com. Retrieved on 2010-11-18.
  37. Approaches in modeling the impact of air pollution-induced material degradation (PDF). Retrieved on 2010-11-18.
  38. Ed. Hatier (1993). Acid Rain in Europe. United Nations Environment Programme GRID Arendal. Retrieved on 2010-01-31.
  39. US Environmental Protection Agency (2008). Clean Air Markets 2008 Highlights. Retrieved on 2010-01-31.
  40. Clean Air Act Amendments of 1990, 42 U.S. Code 7651

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